Шанканай табиғи цеолитінің сорбциялық қасиеттеріне  натрий және магний оксидтерінің әсері

М.М. Мамбетова; М. Анисова; Л.К. Мылтыкбаева; Н.М. Макаева; К. Досумов; Т.В. Шакиева; Г.Е. Ергазиева

doi:10.18321/cpc23(2)153-161

Authors

M.M. Mambetova Institute of Combustion Problems, Bogenbai Batyr St. 172, Almaty, Kazakhstan; Al-Farabi KazNU, Institute of New Chemical Technologies and Materials, Al-Farabi Ave. 71, Almaty, Kazakhstan https://orcid.org/0000-0002-1744-3647
M. Anisova Al-Farabi KazNU, Institute of New Chemical Technologies and Materials, Al-Farabi Ave. 71, Almaty, Kazakhstan https://orcid.org/0000-0001-9622-5164
L.K. Myltykbaeva Al-Farabi KazNU, Institute of New Chemical Technologies and Materials, Al-Farabi Ave. 71, Almaty, Kazakhstan https://orcid.org/0000-0002-0322-0135
N.M. Makaeva Institute of Combustion Problems, Bogenbai Batyr St. 172, Almaty, Kazakhstan; Al-Farabi KazNU, Institute of New Chemical Technologies and Materials, Al-Farabi Ave. 71, Almaty, Kazakhstan https://orcid.org/0000-0002-1638-7460
K. Dosumov Al-Farabi KazNU, Institute of New Chemical Technologies and Materials, Al-Farabi Ave. 71, Almaty, Kazakhstan
T.V. Shakieva Al-Farabi KazNU, Institute of New Chemical Technologies and Materials, Al-Farabi Ave. 71, Almaty, Kazakhstan
G.E. Yergazieva Institute of Combustion Problems, Bogenbai Batyr St. 172, Almaty, Kazakhstan; Al-Farabi KazNU, Institute of New Chemical Technologies and Materials, Al-Farabi Ave. 71, Almaty, Kazakhstan https://orcid.org/0000-0001-9464-5317

DOI:

https://doi.org/10.18321/cpc23(2)153-161

Keywords:

natural zeolite, sorbents, carbon dioxide, CO2 capture, adsorption

Abstract

The paper presents a study of the effect of chemical modification of natural Shankanay zeolite with sodium and magnesium oxides on its sorption properties for carbon dioxide (CO₂) at high temperatures. The sorbents were obtained by mixing followed by the introduction of 10 wt.% Na₂O or MgO. A comprehensive characterization of the samples was carried out using X-ray phase analysis (XRD), scanning electron microscopy (SEM) and temperature-programmed desorption of CO₂ (TPD-CO₂). It was found that the Na₂O modification significantly increases the number of strong basic centers, providing a high sorption capacity of up to 33.5% at 400 °C. The cyclic tests (16 cycles) showed satisfactory stability of the sorbent. The results indicate the promise of zeolite Na₂O/Sh 6/1 as an effective high-temperature CO₂ sorbent.

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